One of my favorite NYFW collections is Badgley Mischka's Spring 2014 Ready to Wear Collection. 

Given the shape and drape of the clothes in the collection, I'm wagering that lightweight wool and silk at least play a role in the fiber content and shoes and bags certainly have leather (at least) components. In sets inspired by the collection, I would look for synthetic materials or natural plant-based fabrics to achieve the look cruelty free. 
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